應注意避免皮膚和(he)眼睛接觸(chu)，避免吸入其蒸氣。在使用(yong)時(shi)應穿戴好個(ge)人(ren)防護裝備(bei)，如(ru)手套、防護眼鏡等。江蘇華政(zheng)生(sheng)物科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)有(you)(you)(you)(you)(you)限(xian)公(gong)(gong)(gong)(gong)司(si)(si)如(ru)您對我們的(de)(de)產品(pin)和(he)服務(wu)感興趣，歡迎隨時(shi)聯系我們，我們將(jiang)竭誠為(wei)您服務(wu)。江蘇華政(zheng)生(sheng)物科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)有(you)(you)(you)(you)(you)限(xian)公(gong)(gong)(gong)(gong)司(si)(si)是一家(jia)科(ke)(ke)(ke)(ke)(ke)(ke)(ke)工貿(mao)一體(ti)的(de)(de)創新(xin)型科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)企業，前(qian)身(shen)為(wei)金壇市(shi)華政(zheng)化工有(you)(you)(you)(you)(you)限(xian)公(gong)(gong)(gong)(gong)司(si)(si)。經過二(er)(er)十幾(ji)年的(de)(de)發展。公(gong)(gong)(gong)(gong)司(si)(si)配備(bei)小(xiao)試、中試實(shi)(shi)驗室和(he)相(xiang)關分(fen)析檢(jian)測設(she)備(bei)，現(xian)(xian)有(you)(you)(you)(you)(you)中高(gao)(gao)級科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)人(ren)員(yuan)(yuan)六名(ming)，業務(wu)上與國(guo)(guo)內(nei)多所高(gao)(gao)校(xiao)及科(ke)(ke)(ke)(ke)(ke)(ke)(ke)研(yan)機構(gou)(gou)有(you)(you)(you)(you)(you)著(zhu)普(pu)(pu)(pu)遍的(de)(de)協(xie)作(zuo)(zuo)。公(gong)(gong)(gong)(gong)司(si)(si)承(cheng)接各(ge)類化學品(pin)定(ding)制(zhi)、愿(yuan)廣大同(tong)仁相(xiang)互學習，共同(tong)發展。江蘇華政(zheng)生(sheng)物科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)有(you)(you)(you)(you)(you)限(xian)公(gong)(gong)(gong)(gong)司(si)(si)是一家(jia)科(ke)(ke)(ke)(ke)(ke)(ke)(ke)工貿(mao)一體(ti)的(de)(de)創新(xin)型科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)企業，前(qian)身(shen)為(wei)金壇市(shi)華政(zheng)化工有(you)(you)(you)(you)(you)限(xian)公(gong)(gong)(gong)(gong)司(si)(si)。經過二(er)(er)十幾(ji)年的(de)(de)發展，現(xian)(xian)已(yi)升級為(wei)江蘇華政(zheng)生(sheng)物科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)有(you)(you)(you)(you)(you)限(xian)公(gong)(gong)(gong)(gong)司(si)(si)。公(gong)(gong)(gong)(gong)司(si)(si)配備(bei)小(xiao)試、中試實(shi)(shi)驗室和(he)相(xiang)關分(fen)析檢(jian)測設(she)備(bei)，現(xian)(xian)有(you)(you)(you)(you)(you)中高(gao)(gao)級科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)人(ren)員(yuan)(yuan)六名(ming)，業務(wu)上與國(guo)(guo)內(nei)多所高(gao)(gao)校(xiao)及科(ke)(ke)(ke)(ke)(ke)(ke)(ke)研(yan)機構(gou)(gou)有(you)(you)(you)(you)(you)著(zhu)普(pu)(pu)(pu)遍的(de)(de)協(xie)作(zuo)(zuo)。公(gong)(gong)(gong)(gong)司(si)(si)配備(bei)小(xiao)試、中試實(shi)(shi)驗室和(he)相(xiang)關分(fen)析檢(jian)測設(she)備(bei)，現(xian)(xian)有(you)(you)(you)(you)(you)中高(gao)(gao)級科(ke)(ke)(ke)(ke)(ke)(ke)(ke)技(ji)(ji)(ji)人(ren)員(yuan)(yuan)六名(ming)，業務(wu)上與國(guo)(guo)內(nei)多所高(gao)(gao)校(xiao)及科(ke)(ke)(ke)(ke)(ke)(ke)(ke)研(yan)機構(gou)(gou)有(you)(you)(you)(you)(you)著(zhu)普(pu)(pu)(pu)遍的(de)(de)協(xie)作(zuo)(zuo)。公(gong)(gong)(gong)(gong)司(si)(si)承(cheng)接各(ge)類化學品(pin)定(ding)制(zhi)、愿(yuan)廣大同(tong)仁相(xiang)互學習，共同(tong)發展。4-戊炔(gui)-1-醇(chun)可溶于(yu)水和(he)常見(jian)的(de)(de)有(you)(you)(you)(you)(you)機溶劑。蘇州5-己炔(gui)-1-醇(chun)炔(gui)醇(chun)量大從優(you)

但(dan)其(qi)反(fan)(fan)應(ying)(ying)(ying)(ying)壓(ya)力(li)高且(qie)(qie)使(shi)用(yong)(yong)溶劑(ji)(ji)(ji)(ji)增加(jia)了產品分(fen)離工序的(de)負擔。的(de)技(ji)(ji)術(shu)方案中(zhong)(zhong)采(cai)用(yong)(yong)高分(fen)散氧(yang)化(hua)(hua)(hua)銦復合(he)的(de)氮摻雜多(duo)孔(kong)炭材料為(wei)(wei)載(zai)體負載(zai)pd作為(wei)(wei)炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)選(xuan)(xuan)擇性(xing)(xing)(xing)加(jia)氫(qing)催(cui)(cui)化(hua)(hua)(hua)劑(ji)(ji)(ji)(ji)，在(zai)反(fan)(fan)應(ying)(ying)(ying)(ying)溫(wen)度30℃、壓(ya)力(li)、有(you)溶劑(ji)(ji)(ji)(ji)乙醇(chun)(chun)(chun)(chun)(chun)存(cun)在(zai)下(xia)，反(fan)(fan)應(ying)(ying)(ying)(ying)2h，炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)轉化(hua)(hua)(hua)率(lv)(lv)為(wei)(wei)100%，相(xiang)應(ying)(ying)(ying)(ying)烯醇(chun)(chun)(chun)(chun)(chun)的(de)選(xuan)(xuan)擇性(xing)(xing)(xing)可達98%。但(dan)該體系反(fan)(fan)應(ying)(ying)(ying)(ying)壓(ya)力(li)較(jiao)(jiao)高，反(fan)(fan)應(ying)(ying)(ying)(ying)時間(jian)較(jiao)(jiao)長。現有(you)技(ji)(ji)術(shu)存(cun)在(zai)以下(xia)不足：（1）反(fan)(fan)應(ying)(ying)(ying)(ying)時間(jian)長；（2）反(fan)(fan)應(ying)(ying)(ying)(ying)壓(ya)力(li)大；（3）使(shi)用(yong)(yong)溶劑(ji)(ji)(ji)(ji)，增加(jia)了分(fen)離成本；（4）催(cui)(cui)化(hua)(hua)(hua)劑(ji)(ji)(ji)(ji)中(zhong)(zhong)貴金屬活(huo)性(xing)(xing)(xing)組分(fen)含(han)量高且(qie)(qie)用(yong)(yong)量大，成本高。技(ji)(ji)術(shu)實現要素(su)：本發(fa)明(ming)所(suo)要解決的(de)技(ji)(ji)術(shu)問題(ti)是克(ke)服上述現有(you)技(ji)(ji)術(shu)存(cun)在(zai)的(de)缺陷，提(ti)供一(yi)(yi)(yi)(yi)種收率(lv)(lv)高，催(cui)(cui)化(hua)(hua)(hua)劑(ji)(ji)(ji)(ji)便宜、用(yong)(yong)量少(shao)、穩(wen)定性(xing)(xing)(xing)高，反(fan)(fan)應(ying)(ying)(ying)(ying)條(tiao)件溫(wen)和，反(fan)(fan)應(ying)(ying)(ying)(ying)時間(jian)短的(de)炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)選(xuan)(xuan)擇性(xing)(xing)(xing)加(jia)氫(qing)制(zhi)烯醇(chun)(chun)(chun)(chun)(chun)的(de)方法。為(wei)(wei)此(ci)，本發(fa)明(ming)采(cai)用(yong)(yong)如下(xia)技(ji)(ji)術(shu)方案：一(yi)(yi)(yi)(yi)種回路反(fan)(fan)應(ying)(ying)(ying)(ying)器中(zhong)(zhong)炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)選(xuan)(xuan)擇性(xing)(xing)(xing)加(jia)氫(qing)制(zhi)烯醇(chun)(chun)(chun)(chun)(chun)的(de)方法，將炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)和鈣鈦礦型(xing)復合(he)氧(yang)化(hua)(hua)(hua)物催(cui)(cui)化(hua)(hua)(hua)劑(ji)(ji)(ji)(ji)投入(ru)回路反(fan)(fan)應(ying)(ying)(ying)(ying)器中(zhong)(zhong)，在(zai)一(yi)(yi)(yi)(yi)定h2壓(ya)力(li)和溫(wen)度下(xia)進行選(xuan)(xuan)擇性(xing)(xing)(xing)氫(qing)化(hua)(hua)(hua)反(fan)(fan)應(ying)(ying)(ying)(ying)，得(de)到對應(ying)(ying)(ying)(ying)的(de)烯醇(chun)(chun)(chun)(chun)(chun)。所(suo)述的(de)鈣鈦礦型(xing)復合(he)氧(yang)化(hua)(hua)(hua)物催(cui)(cui)化(hua)(hua)(hua)劑(ji)(ji)(ji)(ji)為(wei)(wei)la1-mmmmn1-npdno3+δ；m選(xuan)(xuan)自(zi)y、ce、pr中(zhong)(zhong)的(de)一(yi)(yi)(yi)(yi)種；其(qi)中(zhong)(zhong)，m取，n取。所(suo)述炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)的(de)結構(gou)式為(wei)(wei)式（i）；所(suo)述烯醇(chun)(chun)(chun)(chun)(chun)的(de)結構(gou)式為(wei)(wei)式（ii）；其(qi)中(zhong)(zhong)，r1、r2為(wei)(wei)氫(qing)或烴基(ji)。所(suo)述的(de)炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)選(xuan)(xuan)自(zi)2-甲基(ji)-3-丁炔(gui)(gui)-2-醇(chun)(chun)(chun)(chun)(chun)、去氫(qing)芳樟醇(chun)(chun)(chun)(chun)(chun)（3。蘇(su)州5-己(ji)炔(gui)(gui)-1-醇(chun)(chun)(chun)(chun)(chun)炔(gui)(gui)醇(chun)(chun)(chun)(chun)(chun)量大從優4-戊炔(gui)(gui)-1-醇(chun)(chun)(chun)(chun)(chun)通過什么(me)渠道購(gou)買？

而(er)后將樣(yang)品700℃焙燒4h，即可得到鈣鈦礦復合(he)氧(yang)(yang)化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)(ji)h。實(shi)(shi)施(shi)例9催(cui)化(hua)(hua)劑(ji)(ji)的制(zhi)備：按照化(hua)(hua)學計(ji)量摩爾(er)(er)比(bi)la：pr：mn：pd=8:2:、硝酸(suan)鐠、硝酸(suan)錳以(yi)及硝酸(suan)鈀(ba)(ba)，加(jia)(jia)(jia)入(ru)蒸(zheng)餾水中(zhong)(zhong)(zhong)(zhong)(zhong)，再按摩爾(er)(er)比(bi)金(jin)(jin)(jin)屬陽離子：檸(ning)(ning)檬(meng)(meng)酸(suan)=1:，將其(qi)加(jia)(jia)(jia)入(ru)上述(shu)混合(he)鹽(yan)(yan)溶(rong)液(ye)(ye)中(zhong)(zhong)(zhong)(zhong)(zhong)，并(bing)采(cai)用超聲震(zhen)(zhen)蕩(dang)促進(jin)其(qi)溶(rong)解，在(zai)(zai)(zai)80℃下(xia)(xia)水浴(yu)攪(jiao)拌(ban)蒸(zheng)干(gan)(gan)至溶(rong)膠狀態，置(zhi)于烘(hong)(hong)箱中(zhong)(zhong)(zhong)(zhong)(zhong)在(zai)(zai)(zai)120℃下(xia)(xia)干(gan)(gan)燥(zao)4h，而(er)后將樣(yang)品700℃焙燒4h，即可得到鈣鈦礦復合(he)氧(yang)(yang)化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)(ji)i。對比(bi)催(cui)化(hua)(hua)劑(ji)(ji)實(shi)(shi)施(shi)例10催(cui)化(hua)(hua)劑(ji)(ji)的制(zhi)備：按照化(hua)(hua)學計(ji)量摩爾(er)(er)比(bi)la：ce：mn：pd=、硝酸(suan)鈰、硝酸(suan)錳以(yi)及硝酸(suan)鈀(ba)(ba)，加(jia)(jia)(jia)入(ru)蒸(zheng)餾水中(zhong)(zhong)(zhong)(zhong)(zhong)，再按摩爾(er)(er)比(bi)金(jin)(jin)(jin)屬陽離子：檸(ning)(ning)檬(meng)(meng)酸(suan)=1:，將其(qi)加(jia)(jia)(jia)入(ru)上述(shu)混合(he)鹽(yan)(yan)溶(rong)液(ye)(ye)中(zhong)(zhong)(zhong)(zhong)(zhong)，并(bing)采(cai)用超聲震(zhen)(zhen)蕩(dang)促進(jin)其(qi)溶(rong)解，在(zai)(zai)(zai)80℃下(xia)(xia)水浴(yu)攪(jiao)拌(ban)蒸(zheng)干(gan)(gan)至溶(rong)膠狀態，置(zhi)于烘(hong)(hong)箱中(zhong)(zhong)(zhong)(zhong)(zhong)在(zai)(zai)(zai)120℃下(xia)(xia)干(gan)(gan)燥(zao)4h，而(er)后將樣(yang)品700℃焙燒4h，即可得到鈣鈦礦復合(he)氧(yang)(yang)化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)(ji)j。實(shi)(shi)施(shi)例11催(cui)化(hua)(hua)劑(ji)(ji)的制(zhi)備：按照化(hua)(hua)學計(ji)量摩爾(er)(er)比(bi)la：ce：mn：pd=2:8:、硝酸(suan)鈰、硝酸(suan)錳以(yi)及硝酸(suan)鈀(ba)(ba)，加(jia)(jia)(jia)入(ru)蒸(zheng)餾水中(zhong)(zhong)(zhong)(zhong)(zhong)，再按摩爾(er)(er)比(bi)金(jin)(jin)(jin)屬陽離子：檸(ning)(ning)檬(meng)(meng)酸(suan)=1:，將其(qi)加(jia)(jia)(jia)入(ru)上述(shu)混合(he)鹽(yan)(yan)溶(rong)液(ye)(ye)中(zhong)(zhong)(zhong)(zhong)(zhong)，并(bing)采(cai)用超聲震(zhen)(zhen)蕩(dang)促進(jin)其(qi)溶(rong)解，在(zai)(zai)(zai)80℃下(xia)(xia)水浴(yu)攪(jiao)拌(ban)蒸(zheng)干(gan)(gan)至溶(rong)膠狀態，置(zhi)于烘(hong)(hong)箱中(zhong)(zhong)(zhong)(zhong)(zhong)在(zai)(zai)(zai)120℃下(xia)(xia)干(gan)(gan)燥(zao)4h，而(er)后將樣(yang)品700℃焙燒4h。

實(shi)施(shi)(shi)例15催(cui)(cui)化(hua)(hua)劑的(de)(de)(de)制備：按照(zhao)化(hua)(hua)學計量(liang)摩(mo)(mo)爾(er)比(bi)(bi)la：ce：mn=8:2:10稱取一(yi)定量(liang)的(de)(de)(de)硝(xiao)酸鑭、硝(xiao)酸鈰以及硝(xiao)酸錳(meng)(meng)，加(jia)入蒸餾(liu)水中(zhong)，再(zai)按摩(mo)(mo)爾(er)比(bi)(bi)金屬(shu)陽離子(zi)：檸檬酸=1:，將(jiang)其加(jia)入上述混(hun)合(he)(he)鹽(yan)(yan)溶(rong)液中(zhong)，并(bing)采用(yong)超(chao)聲震(zhen)蕩(dang)促(cu)進(jin)其溶(rong)解，在(zai)(zai)80℃下(xia)(xia)水浴(yu)攪拌蒸干(gan)至(zhi)溶(rong)膠(jiao)狀(zhuang)態，置于烘箱中(zhong)在(zai)(zai)120℃下(xia)(xia)干(gan)燥4h，而后將(jiang)樣品700℃焙燒(shao)4h，即(ji)可(ke)得(de)(de)到(dao)鈣鈦(tai)礦復(fu)合(he)(he)氧化(hua)(hua)物(wu)催(cui)(cui)化(hua)(hua)劑δ，記(ji)為催(cui)(cui)化(hua)(hua)劑o。實(shi)施(shi)(shi)例16催(cui)(cui)化(hua)(hua)劑的(de)(de)(de)制備：按照(zhao)化(hua)(hua)學計量(liang)摩(mo)(mo)爾(er)比(bi)(bi)la：mn=1:1稱取一(yi)定量(liang)的(de)(de)(de)硝(xiao)酸鑭以及硝(xiao)酸錳(meng)(meng)，加(jia)入蒸餾(liu)水中(zhong)，再(zai)按摩(mo)(mo)爾(er)比(bi)(bi)金屬(shu)陽離子(zi)：檸檬酸=1:，將(jiang)其加(jia)入上述混(hun)合(he)(he)鹽(yan)(yan)溶(rong)液中(zhong)，并(bing)采用(yong)超(chao)聲震(zhen)蕩(dang)促(cu)進(jin)其溶(rong)解，在(zai)(zai)80℃下(xia)(xia)水浴(yu)攪拌蒸干(gan)至(zhi)溶(rong)膠(jiao)狀(zhuang)態，置于烘箱中(zhong)在(zai)(zai)120℃下(xia)(xia)干(gan)燥4h，而后將(jiang)樣品700℃焙燒(shao)4h，即(ji)可(ke)得(de)(de)到(dao)鈣鈦(tai)礦復(fu)合(he)(he)氧化(hua)(hua)物(wu)催(cui)(cui)化(hua)(hua)劑lamno3+δ，記(ji)為催(cui)(cui)化(hua)(hua)劑p。實(shi)施(shi)(shi)例17反(fan)(fan)應(ying)性(xing)(xing)能(neng)評價(jia)：將(jiang)500g2-甲(jia)基-3-丁(ding)炔-2-醇(chun)和(he)。在(zai)(zai)h2壓(ya)力為，反(fan)(fan)應(ying)溫度為40℃下(xia)(xia)反(fan)(fan)應(ying)30min，將(jiang)液體產物(wu)經氣相(xiang)色(se)譜檢(jian)測分(fen)析，2-甲(jia)基-3-丁(ding)炔-2-醇(chun)轉化(hua)(hua)率為，2-甲(jia)基-3-丁(ding)烯(xi)-2-醇(chun)選擇性(xing)(xing)為。將(jiang)過濾分(fen)離出的(de)(de)(de)催(cui)(cui)化(hua)(hua)劑進(jin)行連續套用(yong)50批，轉化(hua)(hua)率為，選擇性(xing)(xing)為，即(ji)催(cui)(cui)化(hua)(hua)劑有很好的(de)(de)(de)穩(wen)定性(xing)(xing)。實(shi)施(shi)(shi)例18-38在(zai)(zai)實(shi)施(shi)(shi)例10基礎上，改變催(cui)(cui)化(hua)(hua)劑種類、炔醇(chun)種類或反(fan)(fan)應(ying)條件(jian)，其結果如表1所示。10-十一(yi)炔-1-醇(chun)是一(yi)種化(hua)(hua)工中(zhong)間體。

脫(tuo)附(fu)(fu)(fu)(fu)壓(ya)力推薦為(wei)0～。所(suo)述吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)劑(ji)與含(han)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)、丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)的(de)(de)(de)(de)(de)(de)(de)混合氣(qi)(qi)體(ti)(ti)(ti)(ti)的(de)(de)(de)(de)(de)(de)(de)接觸方式(shi)可(ke)以(yi)為(wei)固定床(chuang)(chuang)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)、流化(hua)床(chuang)(chuang)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)、移動床(chuang)(chuang)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)中的(de)(de)(de)(de)(de)(de)(de)至少(shao)一種。作為(wei)推薦，所(suo)述吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)劑(ji)與含(han)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)、丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)的(de)(de)(de)(de)(de)(de)(de)混合氣(qi)(qi)體(ti)(ti)(ti)(ti)的(de)(de)(de)(de)(de)(de)(de)接觸方式(shi)為(wei)固定床(chuang)(chuang)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)，具(ju)體(ti)(ti)(ti)(ti)包(bao)括步驟：在設(she)定的(de)(de)(de)(de)(de)(de)(de)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)溫(wen)度及吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)壓(ya)力下，所(suo)述含(han)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)、丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)的(de)(de)(de)(de)(de)(de)(de)混合氣(qi)(qi)體(ti)(ti)(ti)(ti)通入裝填(tian)有(you)所(suo)述吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)劑(ji)的(de)(de)(de)(de)(de)(de)(de)固定床(chuang)(chuang)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)柱，丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)組(zu)分(fen)(fen)優(you)先穿(chuan)(chuan)透(tou)床(chuang)(chuang)層(ceng)(ceng)(ceng)，從吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)柱出(chu)口(kou)直接獲(huo)得(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)含(han)量(liang)小(xiao)于(yu)(yu)％的(de)(de)(de)(de)(de)(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)氣(qi)(qi)體(ti)(ti)(ti)(ti)，丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)組(zu)分(fen)(fen)在床(chuang)(chuang)層(ceng)(ceng)(ceng)中富集(ji)，脫(tuo)附(fu)(fu)(fu)(fu)即得(de)(de)富丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)氣(qi)(qi)體(ti)(ti)(ti)(ti)。丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)組(zu)分(fen)(fen)與層(ceng)(ceng)(ceng)狀多(duo)孔材料(liao)(liao)相(xiang)互作用弱，吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)量(liang)少(shao)，優(you)先穿(chuan)(chuan)透(tou)固定床(chuang)(chuang)，可(ke)直接獲(huo)得(de)(de)含(han)極低含(han)量(liang)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)(小(xiao)于(yu)(yu)％)的(de)(de)(de)(de)(de)(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)氣(qi)(qi)體(ti)(ti)(ti)(ti)。丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)組(zu)分(fen)(fen)與層(ceng)(ceng)(ceng)狀多(duo)孔材料(liao)(liao)作用力強，在固定床(chuang)(chuang)中富集(ji)，待其穿(chuan)(chuan)透(tou)(吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)飽和)后(hou)，通過減壓(ya)、升溫(wen)、惰性氣(qi)(qi)體(ti)(ti)(ti)(ti)吹掃、產品氣(qi)(qi)吹掃或多(duo)種脫(tuo)附(fu)(fu)(fu)(fu)方法(fa)結合的(de)(de)(de)(de)(de)(de)(de)方式(shi)將(jiang)被吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)的(de)(de)(de)(de)(de)(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)組(zu)分(fen)(fen)解(jie)吸(xi)(xi)(xi)(xi)出(chu)來，獲(huo)得(de)(de)高純度(大于(yu)(yu)％)的(de)(de)(de)(de)(de)(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)氣(qi)(qi)體(ti)(ti)(ti)(ti)。本發(fa)明(ming)與現有(you)技術相(xiang)比(bi)，主要優(you)點包(bao)括：(1)本發(fa)明(ming)提供(gong)了一種采用層(ceng)(ceng)(ceng)狀多(duo)孔材料(liao)(liao)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)分(fen)(fen)離丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)和丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)的(de)(de)(de)(de)(de)(de)(de)新方法(fa)，該材料(liao)(liao)在平衡條(tiao)件下對(dui)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)的(de)(de)(de)(de)(de)(de)(de)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)容量(liang)明(ming)顯高于(yu)(yu)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)，實現丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)和丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)的(de)(de)(de)(de)(de)(de)(de)有(you)效分(fen)(fen)離。(2)本發(fa)明(ming)采用的(de)(de)(de)(de)(de)(de)(de)層(ceng)(ceng)(ceng)狀多(duo)孔材料(liao)(liao)與常規吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)劑(ji)相(xiang)比(bi)，可(ke)對(dui)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)實現排阻，并(bing)具(ju)備較高的(de)(de)(de)(de)(de)(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)炔(gui)(gui)(gui)(gui)吸(xi)(xi)(xi)(xi)附(fu)(fu)(fu)(fu)容量(liang)，從而(er)可(ke)在獲(huo)得(de)(de)高純度的(de)(de)(de)(de)(de)(de)(de)丙(bing)(bing)(bing)(bing)(bing)(bing)(bing)(bing)烯(xi)的(de)(de)(de)(de)(de)(de)(de)同時。2-庚炔(gui)(gui)(gui)(gui)-1-醇(chun)可(ke)以(yi)通過哪里購買？宿遷2-癸炔(gui)(gui)(gui)(gui)-1-醇(chun)炔(gui)(gui)(gui)(gui)醇(chun)什么價格

5-己炔-1-醇國內現在行情(qing)。蘇(su)州5-己炔-1-醇炔醇量(liang)大(da)從優(you)

即(ji)(ji)可得(de)到鈣鈦礦復合(he)(he)(he)氧化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)k。實施例12催(cui)化(hua)(hua)劑(ji)的制(zhi)備：按(an)照化(hua)(hua)學計量摩(mo)爾(er)比(bi)la：ce：mn：pd=2:8:、硝(xiao)酸(suan)(suan)鈰、硝(xiao)酸(suan)(suan)錳(meng)以(yi)及(ji)硝(xiao)酸(suan)(suan)鈀(ba)(ba)，加(jia)(jia)(jia)入(ru)(ru)蒸(zheng)(zheng)餾(liu)水(shui)中(zhong)(zhong)，再按(an)摩(mo)爾(er)比(bi)金屬(shu)陽離(li)子：檸檬酸(suan)(suan)=1:，將其加(jia)(jia)(jia)入(ru)(ru)上述混合(he)(he)(he)鹽溶液(ye)(ye)中(zhong)(zhong)，并(bing)(bing)采(cai)用(yong)超(chao)聲(sheng)震蕩(dang)(dang)促進其溶解，在(zai)(zai)80℃下水(shui)浴(yu)(yu)(yu)攪(jiao)(jiao)拌蒸(zheng)(zheng)干至(zhi)溶膠(jiao)(jiao)狀態(tai)(tai)，置(zhi)于烘(hong)箱中(zhong)(zhong)在(zai)(zai)120℃下干燥4h，而后(hou)(hou)將樣(yang)品700℃焙燒(shao)4h，即(ji)(ji)可得(de)到鈣鈦礦復合(he)(he)(he)氧化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)l。實施例13催(cui)化(hua)(hua)劑(ji)的制(zhi)備：按(an)照化(hua)(hua)學計量摩(mo)爾(er)比(bi)la：ce：mn：pd=2:8:、硝(xiao)酸(suan)(suan)鈰、硝(xiao)酸(suan)(suan)錳(meng)以(yi)及(ji)硝(xiao)酸(suan)(suan)鈀(ba)(ba)，加(jia)(jia)(jia)入(ru)(ru)蒸(zheng)(zheng)餾(liu)水(shui)中(zhong)(zhong)，再按(an)摩(mo)爾(er)比(bi)金屬(shu)陽離(li)子：檸檬酸(suan)(suan)=1:，將其加(jia)(jia)(jia)入(ru)(ru)上述混合(he)(he)(he)鹽溶液(ye)(ye)中(zhong)(zhong)，并(bing)(bing)采(cai)用(yong)超(chao)聲(sheng)震蕩(dang)(dang)促進其溶解，在(zai)(zai)80℃下水(shui)浴(yu)(yu)(yu)攪(jiao)(jiao)拌蒸(zheng)(zheng)干至(zhi)溶膠(jiao)(jiao)狀態(tai)(tai)，置(zhi)于烘(hong)箱中(zhong)(zhong)在(zai)(zai)120℃下干燥4h，而后(hou)(hou)將樣(yang)品700℃焙燒(shao)4h，即(ji)(ji)可得(de)到鈣鈦礦復合(he)(he)(he)氧化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)m。實施例14催(cui)化(hua)(hua)劑(ji)的制(zhi)備：按(an)照化(hua)(hua)學計量摩(mo)爾(er)比(bi)la：mn：pd=10:、硝(xiao)酸(suan)(suan)錳(meng)以(yi)及(ji)硝(xiao)酸(suan)(suan)鈀(ba)(ba)，加(jia)(jia)(jia)入(ru)(ru)蒸(zheng)(zheng)餾(liu)水(shui)中(zhong)(zhong)，再按(an)摩(mo)爾(er)比(bi)金屬(shu)陽離(li)子：檸檬酸(suan)(suan)=1:，將其加(jia)(jia)(jia)入(ru)(ru)上述混合(he)(he)(he)鹽溶液(ye)(ye)中(zhong)(zhong)，并(bing)(bing)采(cai)用(yong)超(chao)聲(sheng)震蕩(dang)(dang)促進其溶解，在(zai)(zai)80℃下水(shui)浴(yu)(yu)(yu)攪(jiao)(jiao)拌蒸(zheng)(zheng)干至(zhi)溶膠(jiao)(jiao)狀態(tai)(tai)，置(zhi)于烘(hong)箱中(zhong)(zhong)在(zai)(zai)120℃下干燥4h，而后(hou)(hou)將樣(yang)品700℃焙燒(shao)4h，即(ji)(ji)可得(de)到鈣鈦礦復合(he)(he)(he)氧化(hua)(hua)物催(cui)化(hua)(hua)劑(ji)δ，記為(wei)催(cui)化(hua)(hua)劑(ji)n。蘇州(zhou)5-己(ji)炔-1-醇(chun)炔醇(chun)量大從優

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